I think you're on the right track as far as sexing them goes.
The one spawning report I know of (other than chance spawnings of
B. splendens was with
B. multiradiatus. The tank was filled to 2" depth with milled sphagnum moss. No gravel, just the moss. You can imagine what the pH would be like (4.5-5.0)
HERE is the one article on breeding
Brochis from
SHANE'S WORLD.
These fish are often captured in swampy areas with still, tannin stained water at ~5.0 pH. You can keep and condition them in more common conditions that will be easier to maintain, but I'd consider the conditions above as a start for any breeding attempt.
BTW: Are you sure they are
B. britskii? How many dorsal fin rays do they have?