If you have some surplus white "eating plates", they'll be useable, but the stuff made for the purpose that you buy in the LFS will be a couple of grades better because it's more porous (as some other posters mentioned).
The glaze that is "dangerous" would mostly be the ones that are:
1. Highly decorated in fancy colours (yellow/red may be Cobolt, blue (I think) may be lead).
2. Non-dishwasher-proof (particularly combined with #1).
If the plate can withstand the chemicals in a dishwasher, it's most likely good in the filter, which is MUCH milder, chemically speaking.
Also, if you're after something cheap, try plain white tiles from the tile-shop. They are less expensive than plates (unless you can get the plates for free by raiding your "old plates cupboard"). Also, they are only glazed on one side.
But there's still lots of problems, just because it's safe for your fish, doesn't mean that it's going to make a good filter. The problem with broken ceramics would be that you may get very poor waterflow through some areas, which means either less filtration (not so bad case) or aneorobic breakdown causing smell and poisonous byproducts(bad case).
If you want cheap filtering, get some polyester "wool" from your LFS. It's a few pounds/dollars/euros.
If you want ceramic filter material, use the stuff that the LFS has, those little ceramic "macarooni" ("tubes" in case you're not pasta literate). It's sure to make good flow through the filter, be nice and friendly to the fish.
It also lasts (almost) forever. If you're really unlucky and need to sterilize it, you can either boil it or use some antibacterial cleaning fluid (bleach or similar). Just make sure you rinse it through THOROUGHLY because it is porous, and chemicals as well as bacteria may well stay in there for some time.
So it's really a one-time investment. [Ok, so I used to loose one or two bits once in a while when I cleaned the filter, so eventually I had to buy another pack to top up, but that's in maybe 10 years or so].
Of course, if you have half a dozen extra large filters, the initial investment starts to amount to something like a mortgage payment
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Mats